Zhaomin Hou 研究室

主宰者：Zhaomin Hou

理化学研究所・RIKEN Center for Sustainable Resource Science

AI 要約（直近 5 年の研究成果）

本研究室は、遷移金属触媒を用いた有機合成化学と高機能ポリマー材料の開発に取り組んでいます。特にスカンジウムやチタンなどの早遷移金属を活用し、C–H結合の直接的な活性化を通じて、従来の方法では得られない複雑な分子構造を効率的に合成することを目指しています。この触媒化学的アプローチにより、医薬品や生理活性物質の合成経路の簡略化、および多官能基を持つ有機化合物の構築が可能になります。同時に、本研究室はこれらの触媒システムを利用してポリマー材料の設計・合成にも注力しています。エチレンと官能基を持つモノマーの共重合により、自己修復能を有する新しい弾性体の開発に成功しています。これらのポリマーは機械的強度と柔軟性を備えるとともに、ダメージを受けた場所を自動的に修復する特性を示し、ウェアラブルデバイスやソフトロボティクスなどの応用が期待されています。また、豊富な化学資源であるジニトロゲンや二酸化炭素といった安定な分子の活性化・変換、さらにはポリエステル廃棄物の化学的リサイクルに関する研究も展開しており、持続可能な化学プロセスの実現を目指しています。

※ AI（Claude）が、公開されている論文要旨から研究の問い・手法・主要な発見を事実情報として抽出・再構成して自動生成しています。誤りを含む可能性があるため、正確性は研究室公式情報でご確認ください。

外部リンク

研究成果（72 件）

[2026] Cascade Coupling of Dinitrogen, Carbon Monoxide, Carbon Dioxide, and Alkynes in a Dititanium Framework
DOI: https://doi.org/10.1021/jacs.6c01768
[2026] Aligned Insulating Cavities for Metal Atom Binding on Conductive Surfaces
DOI: https://doi.org/10.26434/chemrxiv.15000158/v1
[2026] Synthesis of topologically controlled functional polyethylenes: combining C–H activation with copolymerization of ethylene and polar monomers using a scandium catalyst
DOI: https://doi.org/10.1039/d6py00241b
[2026] Scandium-Catalyzed Sequence-Regulated Terpolymerization of Ethylene and Anisylpropylenes toward Self-Healing Elastomers: A Combined Experimental and DFT Study
DOI: https://doi.org/10.1021/acs.macromol.6c00220
[2026] Dinitrogen Functionalization with Allene, Isocyanide, and Carbon Monoxide in a Dititanium Framework
DOI: https://doi.org/10.1021/jacs.6c04550
[2025] Denitrogenative Carbon Skeleton Cleavage and Reorganization of Pyridines by a Trinuclear Titanium Polyhydride Complex
DOI: https://doi.org/10.1021/jacs.5c11238
[2025] Synthesis of [1,3]-thiasilolanes via rare-earth-catalysed intramolecular α-C(sp 3 )–H silylation of alkyl sulphides with hydrosilanes
DOI: https://doi.org/10.1039/d5cc04330a
[2025] Polymer semiconductor blends with remarkably stable semiconducting performance under large and cyclic mechanical deformation
DOI: https://doi.org/10.1038/s41467-025-65327-5
[2025] Diastereo- and Enantioselective Synthesis of Polycyclic Amines by Cascade Cyclization of Aromatic Aldimines with Tethered Alkenes via Scandium-Catalyzed C–H Activation
DOI: https://doi.org/10.1021/jacs.5c08707
[2025] Thioether-Functionalized Self-Healing Polyolefins for Flexible Conductors
DOI: https://doi.org/10.1021/jacs.5c06579

続きを表示（残り 62 件）

[2025] Regioselective Hydropyridylation of Heteroatom-Functionalized Internal Alkenes by Half-Sandwich Rare-Earth Catalysts
DOI: https://doi.org/10.1021/jacs.5c06117
[2025] Metal Synergistic Dual Activation Enables Efficient Transesterification by Multinuclear Titanium Catalyst: Recycling and Upcycling of Polyester Waste
DOI: https://doi.org/10.1002/anie.202505024
[2025] Metal Synergistic Dual Activation Enables Efficient Transesterification by Multinuclear Titanium Catalyst: Recycling and Upcycling of Polyester Waste
DOI: https://doi.org/10.1002/ange.202505024
[2025] Heteroatom‐Assisted Regio‐ and Stereoselective Hydrosilylation of Unsymmetric Internal Alkynes by Scandium Catalyst
DOI: https://doi.org/10.1002/anie.202502665
[2025] Heteroatom‐Assisted Regio‐ and Stereoselective Hydrosilylation of Unsymmetric Internal Alkynes by Scandium Catalyst
DOI: https://doi.org/10.1002/ange.202502665
[2025] Regio- and Stereoselective Hydroalkynylation of Internal Alkynes with Terminal Alkynes by Half-Sandwich Rare-Earth Catalysts
DOI: https://doi.org/10.1021/jacs.4c17210
[2025] Enantioselective [3+2] Annulation of Aldimines with Alkynes by Scandium‐Catalyzed C−H Activation
DOI: https://doi.org/10.1002/anie.202419567
[2025] Synthesis of Rigid Stepladder Polymers via Scandium-Catalyzed Polyspiroannulation of Quinoline with Alkyne
DOI: https://doi.org/10.1021/jacs.4c15046
[2025] Enantioselective [3+2] Annulation of Aldimines with Alkynes by Scandium‐Catalyzed C−H Activation
DOI: https://doi.org/10.1002/ange.202419567
[2025] Regio- and stereoselective C–H alkenylation of pyridines with silyl-substituted internal alkynes using a half-sandwich scandium catalyst
DOI: https://doi.org/10.1039/d5cc03275j
[2025] The Evolution of Precision Polymerization
DOI: https://doi.org/10.1295/kobunshi.74.11_602
[2024] Denitrogenative Ring-Contraction of Pyridines to a Cyclopentadienyl Skeleton at a Dititanium Hydride Framework
DOI: https://doi.org/10.1021/jacs.4c13439
[2024] Divergent Synthesis of Multi‐Substituted Aminotetralins via [4+2] Annulation of Aldimines with Alkenes by Rare‐Earth‐Catalyzed Benzylic C(sp3)−H Activation
DOI: https://doi.org/10.1002/ange.202318203
[2024] (Z)-Selective Isomerization of 1,1-Disubstituted Alkenes by Scandium-Catalyzed Allylic C–H Activation
DOI: https://doi.org/10.1021/jacs.4c06899
[2024] Synthesis of Self-Healing Elastomers by Scandium-Catalyzed Terpolymerization of Ethylene, Styrene, and Dimethylaminophenyl-Substituted Propylene
DOI: https://doi.org/10.1021/acs.macromol.4c00819
[2024] Dielectric and Structural Insight Into an Innovative Self-healing Copolymer
DOI: https://doi.org/10.1109/icd59037.2024.10613074
[2024] Hydroamination of alkenes with dinitrogen and titanium polyhydrides
DOI: https://doi.org/10.1038/s41586-024-07694-5
[2024] Dinitrogen Cleavage and Multicoupling with Isocyanides in a Dititanium Dihydride Framework
DOI: https://doi.org/10.1021/jacs.4c02905
[2024] Regio- and Diastereoselective Annulation of α,β-Unsaturated Aldimines with Alkenes via Allylic C(sp3)–H Activation by Rare-Earth Catalysts
DOI: https://doi.org/10.1021/jacs.4c02144
[2024] Catalytic ammonia synthesis on HY-zeolite-supported angstrom-size molybdenum cluster
DOI: https://doi.org/10.1039/d3sc05447k
[2024] Synthesis of Tough and Fluorescent Self-Healing Elastomers by Scandium-Catalyzed Terpolymerization of Pyrenylethenylstyrene, Ethylene, and Anisylpropylene
DOI: https://doi.org/10.1021/jacs.3c12342
[2024] Divergent Synthesis of Multi‐Substituted Aminotetralins via [4+2] Annulation of Aldimines with Alkenes by Rare‐Earth‐Catalyzed Benzylic C(sp3)−H Activation
DOI: https://doi.org/10.1002/anie.202318203
[2023] Diastereo‐ and Enantioselective Hydrophosphination of Cyclopropenes under Lanthanocene Catalysis
DOI: https://doi.org/10.1002/ange.202308488
[2023] Polymerization of α-olefins and their copolymerization with ethylene by half-sandwich scandium catalysts with an N-heterocyclic carbene ligand
DOI: https://doi.org/10.1039/d2py01526a
[2023] Intrinsically self-healing ethylene-anisylpropylene copolymer as a candidate material for innovative electrical insulation layers
DOI: https://doi.org/10.1016/j.polymertesting.2023.108315
[2023] Dielectric, Thermal and Mechanical Properties of a Sequence-Regulated Ethylene/Anisylpropylene Copolymer
DOI: https://doi.org/10.1109/ceidp51414.2023.10410502
[2023] Aza-Michael Addition of Dinitrogen to α,β-Unsaturated Carbonyl Compounds in a Dititanium Framework
DOI: https://doi.org/10.1021/jacs.3c08715
[2023] Regioselective Carbozincation and Further Functionalization of Allenamides Catalyzed by an N‐Heterocyclic Carbene (NHC)‐Copper Complex
DOI: https://doi.org/10.1002/ajoc.202300372
[2023] Dinitrogen Activation and Addition to Unsaturated C−E (E=C, N, O, S) Bonds Mediated by Transition Metal Complexes
DOI: https://doi.org/10.1002/ange.202218606
[2023] Enantioselective Synthesis of 1-Aminoindanes via [3 + 2] Annulation of Aldimines with Alkenes by Scandium-Catalyzed C–H Activation
DOI: https://doi.org/10.1021/jacs.3c06482
[2023] Hydrodeoxygenative Coupling and Transformation of Aldehydes at a N2-Derived Tetranuclear Titanium Imide/Hydride Framework
DOI: https://doi.org/10.1021/jacs.3c05525
[2023] Diastereo‐ and Enantioselective Hydrophosphination of Cyclopropenes under Lanthanocene Catalysis
DOI: https://doi.org/10.1002/anie.202308488
[2023] C–H functionalization with alkenes, allenes, and alkynes by half-sandwich rare-earth catalysts
DOI: https://doi.org/10.1016/j.tet.2023.133323
[2022] Regioselective Benzylic C–H Alumination and Further Functionalization of 2-Alkylpyridines by Yttrium Catalyst
DOI: https://doi.org/10.1021/acscatal.2c04396
[2022] Electrical Strength Tests of a Self-healable Copolymer Based on Ethylene and Anisylpropylene
DOI: https://doi.org/10.23919/cmd54214.2022.9991429
[2022] Auto-Tandem Copper-Catalyzed Carboxylation of Undirected Alkenyl C–H Bonds with CO2 by Harnessing β-Hydride Elimination
DOI: https://doi.org/10.1021/jacs.2c10754
[2022] Exo-Selective Intramolecular C–H Alkylation with 1,1-Disubstituted Alkenes by Rare-Earth Catalysts: Construction of Indanes and Tetralins with an All-Carbon Quaternary Center
DOI: https://doi.org/10.1021/acscatal.2c03681
[2022] Regio‐ and Diastereoselective Formal [2+2] Cycloaddition of Allenes with Amino‐Functionalized Alkenes by Rare‐Earth‐Catalyzed C(sp2)−H Activation
DOI: https://doi.org/10.1002/anie.202210624
[2022] Regio‐ and Diastereoselective Formal [2+2] Cycloaddition of Allenes with Amino‐Functionalized Alkenes by Rare‐Earth‐Catalyzed C(sp2)−H Activation
DOI: https://doi.org/10.1002/ange.202210624
[2022] Making Polyisoprene Self‐Healable through Microstructure Regulation by Rare‐Earth Catalysts
DOI: https://doi.org/10.1002/anie.202210023
[2022] Making Polyisoprene Self‐Healable through Microstructure Regulation by Rare‐Earth Catalysts
DOI: https://doi.org/10.1002/ange.202210023
[2022] Regio- and Diastereoselective Formal [2+2] Cycloaddition of Allenes with Amino-Functionalized Alkenes by Rare-Earth-Catalyzed C(Sp2)-H Activation
[2022] Dinitrogen activation and transformation by multimetallic polyhydride complexes
DOI: https://doi.org/10.1016/j.ccr.2022.214766
[2022] Phosphine‐Functionalized Syndiotactic Polystyrenes: Synthesis and Application to Immobilization of Transition Metal Nanoparticle Catalysts
DOI: https://doi.org/10.1002/chem.202202113
[2022] Living 3,4-Isoselective (Co)polymerization of Biobased β-Farnesene Catalyzed by Phosphine-Functionalized Fluorenyl Rare-Earth Metal Catalysts
DOI: https://doi.org/10.1021/acs.macromol.2c00887
[2022] Dinitrogen Cleavage and Functionalization with Carbon Dioxide in a Dititanium Dihydride Framework
DOI: https://doi.org/10.1021/jacs.2c01851
[2022] Synthesis of allylanilines via scandium-catalysed benzylic C(sp3)–H alkenylation with alkynes
DOI: https://doi.org/10.1039/d2cc02489f
[2022] Scandium-catalyzed stereoselective block and alternating copolymerization of diphenylphosphinostyrenes and isoprene
DOI: https://doi.org/10.1039/d2py00290f
[2021] Regio‐ and Diastereoselective [3+2] Annulation of Aliphatic Aldimines with Alkenes by Scandium‐Catalyzed β‐C(sp3)−H Activation
DOI: https://doi.org/10.1002/anie.202115996
[2021] Regio‐ and Diastereoselective [3+2] Annulation of Aliphatic Aldimines with Alkenes by Scandium‐Catalyzed β‐C(sp3)−H Activation
DOI: https://doi.org/10.1002/ange.202115996
[2021] Theoretical mechanistic insights into dinitrogen cleavage by a dititanium hydride complex bearing PNP-pincer ligands
DOI: https://doi.org/10.1039/d1dt03852d
[2021] Modular Access to Spiro-dihydroquinolines via Scandium-Catalyzed Dearomative Annulation of Quinolines with Alkynes
DOI: https://doi.org/10.1021/jacs.1c10743
[2021] Terpolymerization of Ethylene and Two Different Methoxyaryl‐Substituted Propylenes by Scandium Catalyst Makes Tough and Fast Self‐Healing Elastomers
DOI: https://doi.org/10.1002/anie.202111161
[2021] Terpolymerization of Ethylene and Two Different Methoxyaryl‐Substituted Propylenes by Scandium Catalyst Makes Tough and Fast Self‐Healing Elastomers
DOI: https://doi.org/10.1002/ange.202111161
[2021] Enantioselective C–H Alkenylation of Ferrocenes with Alkynes by Half-Sandwich Scandium Catalyst
DOI: https://doi.org/10.1021/jacs.0c13166
[2021] Synthesis and Structure Diversity of Half‐Sandwich Rare Earth Dialkynyl Complexes
DOI: https://doi.org/10.1002/hlca.202100197
[2021] Synthesis of <scp>bromine‐functionalized</scp> polyolefins by <scp>scandium‐catalyzed</scp> copolymerization of <scp>10‐bromo‐1‐decene</scp> with ethylene, propylene, and dienes
DOI: https://doi.org/10.1002/pol.20210488
[2021] N‐Monomethylation of Amines with Methanol by Syndiotactic Poly(aminostyrene)‐supported Palladium Nanoparticle Catalyst
DOI: https://doi.org/10.1002/ajoc.202100339
[2021] Application of Simultaneous Measurement System Combining Wide Q-Range Small-Angle Neutron Scattering and Polarized Fourier Transform Infrared Spectroscopy: Cocrystal of Syndiotactic Polystyrene with Methyl Benzoate
DOI: https://doi.org/10.7566/jpscp.33.011076
[2021] Theoretical Studies of Rare-Earth-Catalyzed [3 + 2] Annulation of Aromatic Aldimine with Styrene: Mechanism and Origin of Diastereoselectivity
DOI: https://doi.org/10.1021/acs.joc.0c03060
[2021] Synthesis of Thermoplastic Elastomers by Yttrium-Catalyzed IsospecificTrans-1,4-Polymerization of (E)-1,3-Pentadiene
DOI: https://doi.org/10.1246/bcsj.20210026
[2021] Synthesis and Properties of Self-healing Polyolefin
DOI: https://doi.org/10.2324/gomu.94.52

科研費（0 件）

まだデータがありません（KAKEN 取り込み後に表示）。

所属学会・役職（0 件）

まだデータがありません（学会データ連携後に表示）。

AI 要約（直近 5 年の研究成果）

外部リンク

関連研究室(8 件)

研究成果（72 件）

科研費（0 件）

所属学会・役職（0 件）